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Dave I suspect that the Fireline has a waxy coating on it, which doesn't do well with knots in general, much like Nanofil and other waxed braids; especially in the small kg strengths. What I do to stop the slippage is use the 7 turn Uni to Fig 8, which is a stopper knot, where 2 knots butt up against each other. There's not much chance of slipping with these. It's very frustrating to find a knot that works though.
This is the recommended knot from the Berkley website. Looks like a Doubled Albright knot (Modified Albright).
I have fished fireline extensively and the 7 turn uni to figure 8 works brilliantly. Never had a single failure